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Document Details
Document Type
:
Article In Journal
Document Title
:
Desymmetrization of Meso-Diamine with Enantiopure 3-N,N-Diacylaminoquinazolin-4(3H)-Ones
إعادة اكتساب التماثل لمركب ميزو ثنائي أمين بمركب ن ، ن - ثنائي أستيل أمينوكينو أكزالين - 4 - ( 3- هـ )- أون
Subject
:
Chemistry
Document Language
:
English
Abstract
:
The title compounds (DAQs) are chiral when the two N-acyl groups are different because of the absence of rotation around the N–N bond (a chiral axis). Enantiopure DAQs have been obtained by incorporation of a chiral centre in enantiopure form bearing a chiral substituent in the 2-position of the quinazolinone, followed by separation of diastereoisomers. One of these diastereoisomers reacts with meso-diamine to give N-(2-aminocyclohexyl)benzamide (>95%ee).
ISSN
:
1012-1319
Journal Name
:
Science Journal
Volume
:
19
Issue Number
:
1
Publishing Year
:
1428 AH
2007 AD
Number Of Pages
:
11
Article Type
:
Article
Added Date
:
Sunday, October 11, 2009
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
عبدالله غدران السهيمي
Abdullah G. M. Al-Sehemi
Researcher
Files
File Name
Type
Description
22689.pdf
pdf
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